Cobaltite
Rare cobalt arsenide sulfide, key source of strategic cobalt.
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Cobaltite is a mineral combining arsenic and sulfur, with the chemical makeup CoAsS. It gives its name to the cobaltite group, whose members share a crystal structure similar to pyrite (FeS₂). The mineral was documented in 1797 by Klaproth. Its name derives from the element cobalt, which traces back to the German word Kobold, meaning an "underground spirit" or "goblin." The idea of "bewitched" minerals arose because cobaltite and related cobalt ores resisted medieval smelting techniques, often releasing foul-smelling, toxic gases.
In its natural form, cobaltite appears as a tetartoid—a type of dodecahedron with chiral tetrahedral symmetry. Impurities can include up to 10% iron and varying amounts of nickel. Although uncommon, it is extracted as an important source of the strategically valuable metal cobalt. It is found in high-temperature hydrothermal deposits and contact metamorphic rocks, alongside minerals such as magnetite, sphalerite, chalcopyrite, skutterudite, allanite, zoisite, scapolite, titanite, and calcite, as well as many other cobalt-nickel sulfides and arsenides.
Lore & Background
The name 'cobaltite' traces back to the element cobalt, which itself comes from the German term Kobold, meaning an 'underground spirit' or 'goblin.' This connection arose because cobaltite and other cobalt ores resisted medieval smelting methods, often producing foul-smelling, poisonous fumes—hence the notion of 'bewitched' minerals. A variety containing much iron replacing cobalt, known as ferrocobaltite (German: Stahlkobalt), was found at Siegen in Westphalia. In India, crystals from Khetri in Rajasthan were used under the name sehta by local jewellers to produce a blue enamel on gold and silver ornaments.
Reader's Guide
Cobaltite is mined as a significant source of the strategically important metal cobalt, despite its rarity. It occurs in high-temperature hydrothermal deposits and contact metamorphic rocks, often alongside magnetite, sphalerite, chalcopyrite, skutterudite, allanite, zoisite, scapolite, titanite, and calcite, as well as numerous other Co–Ni sulfides and arsenides. To separate cobaltite from other minerals, selective, pH-controlled flotation methods are used, with cobalt recovery usually involving hydrometallurgy. It can also be processed with pyrometallurgical methods, such as flash smelting.
Secondary weathering incrustations of erythrite, a hydrated cobalt arsenate, are common. Major deposits are found in Sweden, Norway, Germany, Cornwall (England), Canada, La Cobaltera (Chile), Australia, the Democratic Republic of the Congo, and Morocco. Crystals from Khetri in Rajasthan, India, were used under the name sehta by Indian jewellers to produce blue enamel on gold and silver ornaments.
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Sources
Compiled from Wikipedia and the sources listed below. Text from Wikipedia is available under CC BY-SA 4.0; this entry is adapted from it.
- Wikipedia: Cobaltite (CC BY-SA 4.0).
- Word definitions: the Codexery glossary, each quoted from its Wikipedia article.
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